CCLP Chevron Coal Liquefaction Process CCS Carbon capture and storage CO Carbon monoxide CO 2 Carbon dioxide CPI OPECConsumer Price Index CTL Coaltoliquids DCL Direct coal liquefaction DME Dimethyl ether DOD Department of Defense DOE Department of Energy EDS Exxon Donor Solvent ...
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We have launched ISKG for indirect coal liquefaction process, its oriented applications are of great significance in optimizing HAZOP, strengthening industrial safety and popularizing safety prevention awareness. Section 2 is the related work, which mainly reviews HAZOP and KG. Section 3 is the method, we elaborate the development process of ...
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The FischerTropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons. In the usual implementation, carbon monoxide and hydrogen, the feedstocks for FT, are produced from coal, natural gas, or biomass in a process known as gasification.
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Ironbased catalysts are promising catalysts in the direct coal liquefaction (DCL) process as they are inexpensive and environmentally friendly. However, most such ironbased catalysts show relatively low activity in coal conversion and oil yield. Common techniques for the synthesis of these catalysts with excellent catalytic performance remain a substantial challenge. We present a simple ...
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This article is cited by 32 publications. Subhashini Vashisth,, Vimal Kumar, and, Krishna D. P. Nigam. A Review on the Potential Applications of Curved Geometries in Process Industry.
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The liquefaction of coal is one of the main ways to realize the clean and efficient utilization of coal. The industrial application process of preparing clean fuels or chemical products from coal mainly includes three methods: direct coal liquefaction, indirect liquefaction and coal pyrolysis. Direct coal liquefaction, in simple terms, is a ...
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Among them, coal liquefaction residue (CLR) is a waste product in the direct liquefaction process of coal . CLR accounts for 2030 wt.% of the mass of raw coal and is rich in polycyclic aromatic hydrocarbons and polyaromatic hydrocarbons and is a mixture which mainly consist of carbon, ash and sulfur. Therefore, CLR can be used as the ...
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Coal liquefaction is a process in which coal is converted into liquid fuels or petrochemicals. There are several processes used to accomplish this task, the two most common being the "indirect route" and the "direct route". [1]
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CoProcessing refers to the combined processing of coal and petroleumderived heavy oil feedstocks. The coal feedstocks used are those typically utilized in direct coal liquefaction: bituminous, subbituminous, and lignites. Petroleumderived oil, is typically a petroleum residuum, containing at least 70 W% material boiling above 525{degrees}C.
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Coal resources have been used to produce liquid transportation fuels by several process routes collectively referred to as coal liquefaction or, more generally stated, as coal to liquids (CTL). Early records of coal conversion to liquid fuel date to 1913 and an extraction process developed by Friedrich Bergius in Germany [ 7 ].
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Conversion of raw coal to distillate liquid and gaseous hydrocarbon products by solvent liquefaction in the presence of molecular hydrogen employing recycle of mineral residue is commonly performed at a higher thermal efficiency than conversion of coal to pipeline gas in a gasification process employing partial oxidation and methanation reactions.
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In this study, coal fly ash was functionalized, using a simple onestep process (loading with Al3+ and sulfonation), to yield a solid acid catalyst (S/AlCFA) with strong acid sites. The catalyst was then used to produce furfural from xylose in a biphasic system (H2O(NaCl)/tetrahydrofuran). The furfural yield reached 82% at 180 °C60 min with catalyst/xylose ratio of : (w/w). With the ...
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The purpose of coal conversion is the production of alternative fuels, including motor fuels, or the generation of a range of chemicals from coal by process routes, such as gasification, direct and indirect liquefaction, hydropyrolysis, and plasmapyrolysis. The application of these techniques is essential if the large reserves of coal are to be ...
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Based on the liquefaction process, the global coal to liquid (CTL) market is segmented into direct coal liquefaction and indirect coal liquefaction. Indirect coal liquefaction is the most widely used liquefaction technology. This process produces highvalue and cleanburning fuels. Synthetic fuel produced using this technology can be used in ...
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New research from Cornell University shows that liquefied natural gas (LNG) has an even bigger climate footprint than burning coal. The analysis has amplified opposition to a major gas project on ...
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The first commercially available liquefaction process was the Bergius process, developed in Germany as early as 1911 but brought to commercial scale during World War I. This involves mixing coal in an oil recycled from a previous liquefaction run and then reacting the mixture with hydrogen under high pressures ranging from 200 to 700 atmospheres.
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There appears to be considerable potential for improving the processing and economics of direct coal liquefaction through the development and application of highly dispersed catalysts, where the aims are to promote the process of primary coal dissolution, and produce a solubilized product that can be readily upgraded in a second stage over a supported catalyst.
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Coal liquefaction is a process of converting coal into liquid hydrocarbons: liquid fuels and petrochemicals. This process is often known as "Coal to X" or "Carbon to X", where X can be many different hydrocarbonbased products. However, the most common process chain is "Coal to Liquid Fuels" (CTL).
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Coal liquefaction products belong to the new generation of fuel substitutes. However, their composition is different to petroleum fuel specifications: they are mainly composed of naphthenes, aromatics, polycondensed naphthenic and aromatic structures, and heteroatomic compounds (bearing nitrogen or oxygen atoms). Their paraffin content is very low.
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The coal hydrogenation reaction process is simply considered as three steps. In the first step, the smaller molecules associated with coal structure units are released as some gases and water in the condition of solvent and heating. In this step, some weaker bonds of the coal structure units are ruptured to form free radicals. The radicals are stabilized by hydrogen atoms from donor solvent ...
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CO 2 sequestration has been a major concern in application of coal liquefaction technologies because in a typical coal liquefaction process, about 50% carbon in coal is released in the form of CO 2. However, it is important to note that this CO 2 is generated from the gasification or H 2 making unit and is of high purity, more than 98% pure in ...
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Subjects covered include coal liquefaction, coal gasification, desulfurization, hydrocracking, extraction, fluidizedbed combustion, etc. Evaluation and assessment of synthetic fuels made of coal for applications in jet engines are also considered. A great part of papers also include economic consideration. Bibliography data at end of each article.
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Since the late 1970s, coal liquefaction processes have been developed into integrated twostage processes, in which coal is liquefied in the presence of hydrogen in the first stage and the products are upgraded in the second stage.
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Coal liquefaction is a process of changing coal into liquid hydrocarbons: liquid fuels and petrochemicals. This process is often known as "Coal to X" or "Carbon to X", where X can be many different hydrocarbonbased products. However, the most common process chain is "Coal to Liquid Fuels" (CTL)
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Coal liquefaction is very underpowered. It has utility for making blue belts, or if you are low on crude oil. Otherwise it is just worse than advanced oil processing. Liquefaction gives you about 50% petroleum per refinery compared to advanced. Making it comparable to basic oil processing with a giant overhead of cracking and steam production.
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This process is the only coal liquefaction scheme currently in use on a relatively large commercial scale; South Africa is currently using the Fischer−Tropsch process on a commercial scale in their complex. Thus, coal is converted to gaseous products at temperatures in excess of 800°C (1470°F), and at moderate pressures, to produce ...
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The growing demand for petroleum, accompanied by the declining petroleum reserves and the concerns over energy security, has intensified the interest in direct coal liquefaction (DCL), particularly in countries such as China which is rich in coal resources, but short of petroleum. In addition to a general introduction on the mechanisms and processes of DCL, this paper overviews some recent ...
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Coal Liquefaction. Coal liquefaction is a process that converts coal from a solid state into liquid fuels, usually to provide substitutes for petroleum products. Coal liquefaction processes were first developed in the early part of the 20th century but later application was hindered by the relatively low price and wide availability of crude oil and natural gas.
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The only operating process for the 'indirect' liquefaction of coal is South Africa's process, with three operating plant.
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the process to dissolve the coal and to transfer externally produced hydrogen to the coal molecules. Catalytic liquefaction resembles solvent extraction, except that hydrogen is added to the coal with the aid of a catalyst. Figure presents the flow diagram of a typical solvent extraction or catalytic liquefaction plant. These coal ...
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catalysis liquid fuels lignin conversion Introduction Fuels are needed to power electricity and transportation, in the US and the rest of the world. Currently, the bulk of the power and transportation fuels rely on petroleum, coal and natural gas, with some contributions from hydroelectric, nuclear power, biomass and other alternatives.
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Irdi et al. (1998) deashed and gasified DCLR to improve the economy of the direct coal liquefaction process. DCLR can be used as a raw material for preparing hydrogen for the coal liquefaction reaction process. It can be mixed and cogasified with raw coal at a high temperature . Preparation process. Mixing Process.
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2. Effect of liquefaction processing conditions on the formation and quenching of coal free radicals. Fuel, 1980, 59(4): 227232. Article CAS Google Scholar Petrakis L, Grandy D W. Free radicals in coal and coal conversions. 6. Effects of liquefaction process variables on the insitu observation of free radicals.
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The occurrence of sulfur in coal direct liquefaction residue affects its further high quality and high value utilization. Electrochemical desulfurization is characterized by mild reaction conditions, simple operation, easy separation of sulfur conversion products and little influence on the properties of the liquefied residue. An anodic electrolytic oxidation desulphurization experiment was ...
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